Spring 2011 Cumulative Outline

(This will slide around abit as the semester proceeds to accommodate shifts in emphasis. After each lecture, the "Lecture X" hyperlink will connect to that lecture's slide collection. Previews may be found via the "Main Index" under "Preview". When lecture material has corresponding text material, the Chapter and possible Section are indicated in [green]. Be aware that parts of the outline may have no corresponding reading in the text.

Lecture Slides 1. History [Chapter 2]

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Lecture Slides 2. History

Energies

Masses

Lecture Slides 3.

Problems with some results of physical measurements [Chapter 12]

Physics puzzles "solved" by quantization

(Old Quantum Theory)

Physics puzzles "solved" by quantization (continued)
Line spectra, Bohr's Planetary Model, quantized angular momentum [Section 12.4]

(New Quantum Theory)

Lecture Slides 4. (Old Quantum Theory)

Wave Nature of Matter

Electron "spin"[Section 12.10]

Geometries [12.9]

Lecture Slides 5. (New Quantum Theory)

Geometries [12.9]

More outcomes of wave-particle duality

screening and penetration of electrons in the same shell

Many-electron systems

Lecture Slides 6. Many-electron systems

Lecture Slides 7. The Periodic Table (continued)

Lecture Slides 8. Periodic Table (continued)

Lecture Slides 9.

Review for Exam I

Lecture Slides 10. Molecules

Electronegativity [13.2]

Molecular Structure

Lewis Structures [13.10]

Lecture Slides 11. Lewis Structures [13.10]

Lecture Slides12. Molecular Structure

Resonance (Benzene puzzles)

Resonance [13.12]

Lewis structures

Lecture Slides13. Lewis structures

Dipole moments and partial ionic character

Line Structures

Lecture Slides 14.

Acid strengths and pK's

Lecture Slides 15. Molecular Geometries

VSEPR Model [13.13]

Distortions from ideal geometries

Lecture Slides 16. Molecular Geometries

VSEPR Model [13.13]

Distortions from ideal geometries

Dipole Moments in Polyatomic Molecules

Molecular dipoles from "bond" dipoles

Geometric isomerism

Lecture Slides 17. Review for Exam II

Lecture Slides 18. Review for Exam II

Lecture Slides 19. Quantum Theory of the Chemical Bond

Quantum Theory of the Chemical Bond

Molecular orbitals (in "homonuclear diatomic molecules" [14.2,3]

 

Lecture Slides 20. Quantum Theory of the Chemical Bond

Molecular orbitals (in "homonuclear diatomic molecules" [14.2,3]

 

Lecture Slides 21. Quantum Theory of the Chemical Bond

Molecular Orbitals (factors to consider)

Heteronuclear diatomic molecules [14.4]

Lecture Slides 22. Quantum Theory of the Chemical Bond

Molecular Orbitals

Molecular Orbitals in Polyatomic Molecules

Lecture Slides 23. Molecular Orbitals in Polyatomic Molecules (Delocalized Bonds)

Lecture Slides 24. Delocalized Molecular Orbitals

Triatomic molecules

Energy levels and the particle-in-a-box model

Lecture Slides 25. Delocalized Molecular Orbitals

Strained bonds

Metallic bonds [pp. 797-8]

Lecture Slides 26. Review for Exam III

Lecture Slides 27. Review for Exam III

Lecture Slides 28. Intermolecular Interactions

Ideal gases

Real gases (Van der Waals)

Intermolecular Interactions (condensed phases)Real gases (Van der Waals) [16.1, 2]

Induced dipoles

Van der Waals interactions

Lecture Slides 29. Intermolecular Interactions (condensed phases) [16.1, 2]

Van der Waals interactions

Lecture Slides 30. Intermolecular Interactions (condensed phases)

Van der Waals interactions

Lecture Slides 31.

Oxidation Numbers

Transition Metal Chemistry

Tramsition metal ion electron configurations [19.1]

Coordination complexes [19.3]

Isomers Real [19.4]

Lecture Slides 32. Transition metal complexes

Stereoisomers

Geometrical isomers

Optical isomers [19.4]

Observations to explain

Crystal Field Theory [19.6]

Lecture Slides 33. Transition Metal Complexes

Crystal Field theory

Distorting the octahedral geometry

Square Planar geometry

Tetrahedral geometry

Hybrid orbitals and bonding

Lecture Slides 34. Transition Metal Complexes

Hemoglobin

Lecture Slides 35. Review

Lecture Slides 36. Review

Lecture Slides 37. Review