Cumulative Outline

Lecture 1. History

Lecture 2. History

Lecture 3. Energies

Rutherford's atomic model

Mass Spectroscopy

Problems with some results of physical measurements

Lecture 4. (Old Quantum Theory)

Physics puzzles "solved" by quantization

(New Quantum Theory)

Particle-in-a-box model

Lecture 5. Wave Nature of Matter

Particle-in-a-box

Schrodinger's Wave Equation applied to the hydrogen atom, orbitals

Electron "spin"

ms, spin quantum number

Energies and geometries

Lecture 6. More outcomes of wave-particle duality

Lecture 7. Many-electron systems

Lecture 8. The Periodic Table (continued)

Lecture 9.

Electron Configurations and Ionization Energies

Review for Exam I

Lecture 10. Electron Configurations and Ionization Energies

Valence electrons and electron dot structures in atoms

Lewis Structures

Lecture 11. Lewis Structures

Octet Rule

 

Lecture 12. Molecular Structure

Lewis Structures

Exceptions to the Octet Rule

Resonance

Lecture 13. Lewis structures (continued)

Resonance

Line structures

Reaction Heats

Lec ture 14. Lewis structures (continued)

Molecular structure and acid strength

Lecture 15. Polar bonds

Molecular Geometries

Lecture 16. Molecular Geometries (continued)

VSEPR Model

Distortions from ideal geometries

  • effect of lone pairs vs bonding pairs
  • effect of multiple bonds
  • effect of lone single electrons
  • effect of electronegativity differences

Lecture 17. Oxoacids (continued)

Lecture 18. Review for Exam II

Lecture 19. Molecular Geometries

Molecular orbitals (in "homonuclear diatomic molecules")

Lecture 20. Quantum Theory of the Chemical Bond

Molecular orbitals (in "homonuclear diatomic molecules")

Lecture 21. Quantum Theory of the Chemical Bond

Molecular orbitals (in "homonuclear diatomic molecules")

Molecular Orbitals

Lecture 22. Quantum Theory of the Chemical Bond

Molecular Orbitals

Polyatomic Molecules

Lecture 23. Molecular Orbitals in Polyatomic Molecules

Lecture 24. Molecular orbitals (localized, continued)

Molecular orbitals (delocalized)

1,3 butadiene example

Benzene

Lecture 25. Molecular Orbitals (delocalized)

Lecture 26. Review for Exam III

Lecture 27. Molecular Orbitals (delocalized, continued)

Gases

Lecture 28. Intermolecular Interactions

Gases

Induced dipoles

  • Effects of size
  • Effects of shape

Lecture 29. Intermolecular Interactions (condensed phases)

Liquids and Solids

Lecture 30. Intermolecular Interactions

Lecture 31. Oxidation numbers

Transition Metal Chemistry

Lecture 32. Transition metal complexes

Stereoisomers

Optical isomers

Observations to explain

Crystal Field theory

Lecture 33. Transition Metal Complexes

Review for Exam IV

Lecture 34. Transition metals

Lecture 35. Transition Metals

Lecture 36. Hemoglobin